Open Access Open Access  Restricted Access Subscription or Fee Access

Synthesis, Spectral characterization and biocidal activities of Triphenyl antimony (V) halide and methoxide complexes

Ashish Kumar, Brij Kishore Tiwari, Tasneem Sultan, Narendra Deo Pandey, Sahid Suhail Narvi

Abstract


The schiff base ligands N-mono(salicyclidene)-σ-phenylenediamine (spdH) and N-mono(2-hydroxy-1-naphthalidene)-σ-phenylenediamine (hnpdH) and their triorganoantimony (V) complexes were synthesized by conventional method, were characterized by UV, IR and 1H NMR spectral studies which proposed that in the complexes of the ligands spdH and hnpdH, antimony is seven coordinated and in sp3d3 hybridization state with pentagonal bipyramidal geometry.

Full Text:

PDF

References


J.S. Li, G.Q. Huang, Y.T. Wei, C.H. Xiong, D.Q. Zhu, Appl.organomet.Chem., 12, 31-38,1998

G. Ferguson, B. Kaitner, C. Glidewell and S. Smith, J. organomet. Chem. 419, 283-291,1991

M. Fujiwara, M. Imada, A. Bala and H. Matsuda, Tetrahedron Lett. 30, 739-742 1989

L. Yu, Y.Q. Ma, G.C. Wang and J.S. Li, Heteroatom Chem. 15, 32-36, 2004

Ludmila G. de Oliveira, Meiriane M. Silva, Flávia C. S. de Paula, Elene C. Molecules,16, 10314-10323, 2011

Arshad Islam, Jeferson Gomes Da Silva, Filipe Moan Berbet, Sydnei Magno da Silva Molecules,19, 6009-6030,2014

Fahmi et al., IJPSR, 5(12): 5260-5266, 2014

Hassan Keypour1,Shadegg Salehzadeh1 and R. V. Parish Molecules, 7, 140-144, 2002

Abdullah M. Asiri and Khadija O. Badahdah Molecules, 12, 1796-1804,2007

Y.Q. Ma, J.S. Li, Z. Xuan and R. Liu, J. Organomet. Chem. 620, 235-242 ,2001

X.Q. Song, Q.L. Xie and X.N. Fang, Heteroatom Chem. 13, 592-598 ,2002,

J.S. Li, Y.Q. Ma, J.R. Cui and R.O. Wang, Appl. Organomet. Chem. 15, 639-645, 2001

Y.Q. Ma, L. Yu and J.S. Li, Heteroatom Chem. 13, 299-301,2002

Muhammad Kaleem Khosa, Muhammad Mazar, Saqib Ali, Khadija Shahid and Farnaz Malik, Turk. J. Chem. 30, 345 – 354,2006.

A. Saeed, Helv. Chim. Acta. 86, 377-383, 2003

Barry A.L., Procedures for testing of antimicrobial agents in agar media. In: Antibiotics in laboratory medicine,(V. Lorian Ed.), Williams and Wilkins Company, Baltimore, USA, 1980; 1-23. 10.

Bauer, AW et al.: Antibiotic susceptibilities testing by standard single disc diffusion method. Am. J. Clin. Pathol.1966; 45: 493-496.


Refbacks

  • There are currently no refbacks.