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Performance Studies on Solar Photocatalysis and Photo-Fenton Process in Treatment of Polymer Based Oil Produced Water

Feroz Shaik, Khalid Hamed Ali Al Saadi, Dr Lakkimsetty Nageswara Rao, M. J Varghese


The oil produced water is a complex mixture of different organic and inorganic compounds is a major wastewater stream generated during oil and gas production processes. Comparative research study was carried out on the performance of different oxidation processes such as the solar photocatalyst of TiO2 and photo-Fenton for the treatment of low salinity oil produced water including polymer from oil fields in Oman. The treatment efficiency is evaluated in terms of degradation of Total Organic Carbon (TOC) and Chemical Oxygen Demand (COD). The COD and TOC degradation were 79% and 32.2% respectively for an optimum condition of photocatalyst 1g/L TiO2 with reaction time of 4 hours. The optimum condition observed with a reaction time of 2 hours in the solar photo-Fenton (1 g/l H2O2 , 0.2 g/l Fe+2) of COD and TOC degradation were 53.7% and 48.2% respectively.

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C.S. Ong,W.J. Lau, P.S. Goh, B.C. Ng, A.F. Ismail, Investigation of submerged membrane photocatalytic reactor (sMPR) operating parameters during oily wastewater treatment process, Desalination, 353 (2014):48–56.

Eduardo Bessa, Geraldo Lippel Sant’Anna Jr., Márcia Dezotti, Photocatalytic/H2O2 treatment of oil field produced waters, Applied Catalysis B: Environmental 29, (2001): 125–134.

Dheeaa al deen Atallah Aljubourya, Puganeshwary Palaniandy, Hamidi Bin Abdul Aziz and Shaik Feroz, Comparative Study to the Solar Photo-Fenton, Solar Photocatalyst of TiO2 and Solar Photocatalyst of TiO2 Combined with Fenton Process to Treat Petroleum Wastewater by RSM. J Pet Environ Biotechnol 7 (2016): 2157-7463.

Dheeaa al deen Atallah Aljuboury, Puganeshwary Palaniandy, Hamidi Bin Abdul Aziz, Shaik Feroz, Treatment of petroleum wastewater using combination of solar photo-two catalyst TiO2 and photo-Fenton process, Journal of Environmental Chemical Engineering, 3 (2015):1117–1124.

Shamsa Al Sadi, S. Feroz, L. Nageswara Rao, Treatment of Industrial Wastewater by Solar Nano Photocatalysis, International Journal of ChemTech Research, (2015):8(7),177-182.

Waste water Treatment using Solar UV Radiation, CSEM-UAE Innovation Center LLC.

Tânia F.C.V. Silva, Amélia Fonseca, Isabel Saraiva b, Rui A.R. Boaventura a, Vítor J.P. Vilar, “Scale-up and cost analysis of a photo-Fenton system for sanitary landfill leachate treatment”, Chemical Engineering Journal (2016): 283,76–88.

M. A. Tony, Y. Q. Zhao, P. J. Purcell, M. F. El-Sherbiny, “Evaluating the photo-catalytic application of Fenton's reagent augmented with TiO2 and ZnO for the mineralization of an oil-water emulsion”, Journal of Environmental Science and Health (2009): 44 (5),488-493.

G. Luna Mark Daniel, R. M. Luna Briones, Su Chia-Chi, Lu Ming-Chun, “Kinetics of acetaminophen degradation by Fenton oxidation in a fluidized-bed reactor”, Chemosphere (2013):90,1444–1448.

Zarei, Mahmoud, Alireza Khataee, Mehrangiz Fathinia, Fardin Seyyednajafi, Heidar Ranjbar, “Combination of nano photocatalysis with electro-Fenton like process in the removal of phenol from aqueous solution: GC analysis and response surface approach”, International Journal Industrial Chemistry (2012): 3 (1)27-28.


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