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Application of Acid Treated Carbon Derived from Biomass (Lantana camara) for Removal of Phenol from Aqueous Solutions

Pushpa Jha, Priya Rani

Abstract


The presence of phenolic compounds is toxic and harmful to human health and aquatic life. Five biomass: cotton stalk, rice straw, bagasse, wheat straw and Lantana camara were characterized. Based on characterization and availability, Lantana camara (LC) was selected for study as an adsorbent. LC and activated Lantana camara (ALC) were further characterized and studied for their suitability as the commercial adsorbent for removal of phenol. Equilibrium study on ALC was done based on optimized conditions of adsorbent dosage, pH, initial phenol concentration, shaking speed and time of contact. The sorption isotherm fits Freundlich isotherm indicating multilayer adsorption. Maximum sorption capacity is 828.562 mg/g indicating its capacity comparable to commercial grade carbon. The kinetic data fits pseudo-first-order kinetics indicating there is a possibility of physical adsorption.

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References


J.M. Diasa, M.C.M. Alvim-Ferraza, M.F. Almeida, J. Rivera-Utrillab, M. SánchezPolob. Waste materials for activated carbon preparation and its use in aqueous phase treatment: a review, J Environ Manage. 2007; 85: 833–46p.

P.V.R. Iyer, T.R. Rao, P.D. Grover. Biomass Thermo-Chemical Characterization. Delhi: Chemical Engineering Department, IIT; 2002, 45p.

A. Bhatnagar, A.K. Minocha. Adsorptive removal of 2,4-dichlorophenol from water utilizing Punica granatum peel waste and stabilization with cement, J Hazard Mater. 2009; 168: 1111–7p.

A. Bhatnagar, M. Sillanpää, A. Witek-Krowiak. Agricultural waste peels as versatile biomass for water purification – a review, J Chem Eng. 2015; 270: 244–71p.

Abdelkreem M. Adsorption of phenol from industrial wastewater using olive mill waste, J APCBEE Proc. 2013; 5: 349–57p.

M. Ahmaruzzaman, D.K. Sharma. Adsorption of phenols from wastewater, J Colloid Interface Sci. 2005; 287: 14–24p.

M. Ahmaruzzaman. Adsorption of phenolic compounds on low-cost adsorbents, J Adv Colloid Interface Sci. 2008; 143: 48–67p.

A.S. Stasinakis, I. Elia, A.V. Petalas, C.P. Halvadakis. Removal of total phenols from olive-mill wastewater using an agricultural by-product, olive pomace, J Hazard Mater. 2008; 160(2-3): 408–13p.

B.H. Hameed, A.A. Rahman. Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material, J Hazardous Mater. 2008; 160(2008): 576–81p.

F.A. Banat, B. Al-Bashir, S. Al-Asheh, O. Hayajneh. Adsorption of phenol by bentonite, Environ Pollut. 2000; 107: 391–8p.

U. Beker. Adsorption of phenol by activated carbon: Influence of activation methods and solution Ph, Energy Convers Manage. 2010; 51: 235–40p.

C.R. Girish, V. Ramachandra Murty. Adsorption of phenol from wastewater using locally available adsorbents, J Environ Res Dev. 2012; 6(3A): 763–72p.

B. Dass, P. Jha. Adsorption of phenol by a biomass (Acacia nilotica Branches) based activated carbon for water purification, R J Pharm Biol Chem Sci. 2015; 6(4): 1361–72p.

V. Srihari, A. Das. Adsorption of phenol from aqueous media by an agro-waste (Hemisdumus indicus) based activated carbon, Appl Ecol Environ Res. 2009; 7(1): 13–23p.

ASTM International, D4607-94 (2011).

S. Siggia. Quantitative Organic Analysis via Functional Groups. 3rd Edn., New Jersey: John Wiley & Sons; 1967, 54p.


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