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Synthesis, Spectral and Magnetic Moment Studies of Mixed Ligand Complexes of Hydroxamic Acids with Potassium Hexathiocyanato Vanadium (II) Tetra Hydrate

Ajay Agarwal

Abstract


Preparation and characterization of several hydroxamic acids of 3,4,5-trimethoxy benzohydroxamic acids(TMBHA), N-phenyl–3,4,5-trimethoxy benzohydroxamic acid(PTMBHA), 3,4-dimethoxy benzohydroxamic acid(DMBHA) and N-phenyl-3,4-dimethoxy benzohydroxamic acid(PDMBHA) were prepared and reacted with potassium hexathiocynato vandate (II) K4[V(NCS)6].3H2O tetra hydrate. The mixed ligand complexes of hydroxamic acids characterized with the help of repeated melting point identification, by I.R. studies, magnetic moment, molar conductance’s and by elemental analysis (C, H and N). The geometry of complexes were found to be octahedral .On the basis of these e facts the structure of the metal complexes found to be K2 [M(L’)2(L1)2], K3[M(L’)4(L2)], K2[M(L’)2(L3)2] and K3[M(L’)4(L4)]. Keywords: hydroxamic acids, potassium hexathiocynato vanadate (II) and mixed ligand complexes

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Y.K.Agarwal, Russ.Chem.Rev, Engl.Transl., 488, 948, 1979.

M.C.Pirrungand, C.R.Raetz,J. Am.Chem.Soc.,125,1575,2003.

R.Zamora,A.Grzesiok,H.Weber M.Feelisch,Biochem,312(2),333-329,1995.

R.Brammer, J.Buckels,S.Bramhall, Cancer. Int. J.Clin.Pract., 54(6), 373-381, 2000.

R.C.Mishra, R. Tripathi, D. Katiyar, N. teariD. Singh, R. P. Tripathi, Bioionrg. Med. Chem., 1(24), 5363-5374, 2003.

M.J.Miller, Chem.Rev., 89,1563-1579,1989.

A.J.Middleton,D.S.Cole,K.D.Mc Donald,J.Antibiot.(Tokyo),31,110-5,1978.

M.J.Miller, Acc.Chem.Res., 1949,1978.

D.G. Tang et. al., Biochem. Biophys.Res. Commun., 242,380-384, 1978.

M.J.Rao,J.Inorg. Biochem., 15,46(3),207-214,1992.

J. H.Musser, A.F.Kreft,R.H.W.Bender, J.Med.Chem.,333,240,1990.

Sh.Odake, T.Okayama, M.Obata, Chem. Pham. Bull., 39, 1489, 1991.

I.G. Makara, Trends Biochem. Sci., 5, 92, 1980.

R. Wever, K. Kustin, Adv. Inorg. Biochem., 35, 103,1990.

Natajan Raman, Abraham Selvan, Journal of Molecular Structure, 985, 2-3, 31,173-183, 2011.

H.M.Niemeyer, M.J.Miller,J.Org.Chem.,65,4838,2000.

S.W.Taylor, B.Kammerer, E. Bayer, Chem. Rev., 97,333– 346,1997.

R.E.Berry, E.M.Armstrong, R.L Beddoes, D. Collison, S.NErtok, M. Helliwell, C.D.Garner Angew Chem. Int. Ed., 38,795– 797,1999.

K.H.Thompson, J.H.McNeil, C.Orvig, Chem.Rev., 99,2561,1999.

K.H.Thompson,J.M.Jong,S.J.Retting,E.Shuter,V.G.Yuen,J.H.McNeil,C.Orvig,Inorg.Chem.,38,2288,1999.

M.Hiromura, H.Sakurai, Chem.Biodiverse, 5, 1615-1621, 2008.

J.HMcNeill, V.G. Yuen, H.R. Hoveyda, C,J. Orvig, J. Med Chem., 35, 1489, 1992.

E. Friden, Scientific American, 227, 52, 1972.

C.E. Heyliger, A.G. Tahilian, J.H.M. Neill, Science, 227, 52, 1985.

Michael W King, Introduction to Cholesterol Metabolism Thermedical Biochemistry Org. LLC. 1996, 2013.

F.H.Neilson,E.O.Uthus,”The Essential and Metabolism of Vanadium .Vanadium in Biological Systems,Physcology and Biochemistry, Edited by N.D.Chasteren (Kluwer Academic Publisher,The Netherlands)1990.

A.Earnshaw, “Introduction to Magneto chemistry”, Academic Press: London, 1968.

G.Brauer, F.Enke,”Hand Book of Preparative Chemistry”, Vol II, Verlage, Stuttgart, 155, 1962.

E.O.Fischer, H. Leipfinger, Z.Naturforsch., 106, 353, 1955.

S.Herzog, Z. Inorg.Allgem.Chem., 294, 155, 1958.

B. N. Figgis, J.Lewis, Prog .Inorg.Chem., 6,34,1963.

B.N.Figgis, J.Lewis, Prog. Inorg., Chem. 6,59,1963.

C.J.Ballhausen, Introduction to Ligand Field Theory, Mc Graw Hill, New York, 1962.

Yin Zhi-gang, Central South University, 50, 2010.

K. Nakamoto,” Infra red Spectra of Magnetic and Coordination compounds, 77, (Wiley,New York),1963.

L.J.Bellamy “The infra-red Spectra of Complex Compounds (Methyen, London), 212, 1954.

D.Hadzi, D.Prevorsek,Spectrochim. Acta, 10,38,1957.

N.F. Bogdanova, A.V. Klebanov, L.E. Ermakova, M.P. Sidorova, D.A. Aleksandrow,Colloid Journal,66(4), 409−417, 2004.

C.K.Narula,V.D.Gupta, J. Indian Chem. Soc.,Vol.II,230-232,1980.

P.C.H. Mitchell, R.J.P. Williams, J. Chem. Soc., 1912.1960.

B.G. Bannet, D. Nichollas, Chem. Soc.,(A),1204,1971.

Ajay Agarwal, Virendra Mishra, Babita Agarwal, Rahul Pathak, National conference RDEECE, Sponsored by IEE, 2016.

C.D.Flint, A.D.Matthews, J.Chem.Soc.Faraday.Trans, 70, 1301, 1974.

Doyel Bose,S.K.Hafijur Rahman,Rajarshi Ghosh,Golam Mostafa, Joan Ribas, Chen Hsiung Hung, Barindra K. Ghosh,Polyhedron,25,3,645-653, 2006.


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