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Synthesis, Spectral characterization and biocidal activities of Triphenyl antimony (V) halide and methoxide complexes

Ashish Kumar, Brij Kishore Tiwari, Tasneem Sultan, Narendra Deo Pandey, Sahid Suhail Narvi


The schiff base ligands N-mono(salicyclidene)-σ-phenylenediamine (spdH) and N-mono(2-hydroxy-1-naphthalidene)-σ-phenylenediamine (hnpdH) and their triorganoantimony (V) complexes were synthesized by conventional method, were characterized by UV, IR and 1H NMR spectral studies which proposed that in the complexes of the ligands spdH and hnpdH, antimony is seven coordinated and in sp3d3 hybridization state with pentagonal bipyramidal geometry.

Keywords: halide, methoxide complexes, triphenylantimony (V)

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