Kinetics of oxidation of mixture of oxalic acid and glutaric acid by chromic acid in presence of sodium chloride and potassium chloride

Authors

  • Mamta Mishra Assistant Professor, Department of Applied Science, GL Bajaj Institute of Technology and Management, Greater Noida, Uttar Pradesh
  • Ashish Kumar Associate Professor, Department of Applied Science and Humanities, G.L. Bajaj Institute of Technology and Management, Greater Noida-201308, Uttar Pradesh, India
  • Brij K Tiwari Assistant Professor, Department of Applied Science, GL Bajaj Institute of Technology and

Abstract

Effect of Sodium Chloride and Potassium chloride on the co-oxidation of oxalic Acid and glutaric Acid by Chromic Acid has been studied. The products are carbonyl di carboxylic Acid and Carbon dioxide. The rate of oxidation decreases with the increase in the concentration of Sodium Chloride and Potassium Chloride. It is found that Potassium Chloride is the most effective in retarding the reaction rate comparison to Sodium Chloride. The order of reaction is one in presence of Sodium Chloride and Potassium Chloride. The temperature coefficient at three different temperatures, catalytic constant and dielectric constant are determined.

 

Key words: glutaric acid, sodium chloride, potassium chloride, kinetics, oxalic acid, glutaric acid.

References

Cite this Article: Mamta Mishra, Ashish Kumar, Brij K. Tiwari. Kinetics of

Oxidation of Mixture of Oxalic Acid and Glutaric acid by Chromic Acid in

Presence of Sodium Chloride and Potassium Chloride. International Journal of Thermodynamics and Chemical Kinetics. 2019; 5(2):4–8p.

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Published

2020-01-22

Issue

Vol. 5 No. 2 (2019)

Section

Articles