Open Access Open Access  Restricted Access Subscription or Fee Access

Synthesis, Characterization and Catalytic Study of Chitosan-Schiff Base Manganese Complex

Jaya T. Varkey, Agiya Cosmos M.C., Pravesh Saini

Abstract


Schiff base is the condensation product formed when a primary amine reacts with a carbonyl compound. The term Schiff base is normally applied to those compounds when they are being used as ligands to form coordination complexes with metal ions. Its formation takes place under acid or base catalysis or with heat. Vanillin Schiff base and Aspartic acid-Salicylaldehyde Schiff bases have been synthesised by
condensation reaction. The synthesized ligands were mixed together to improve the ligand efficiency. The mixed ligand was successfully complexed with metal ion manganese to study its catalytic activity. The structure and properties of the complex have been characterized by spectral and thermal techniques. The catalytic activity and recyclability of the complex has been proved by the efficient
synthesis of Benzimidazole.


Full Text:

PDF

References


Nasira Niyas Surve, Rashmi Shankar, Kabita Saud, Rahul Gupta, Shankerdutt Pandey, Satu T Chavhan, RP Chavhan, Synthesis, Characterization of some Schiff’s bases derived from phenyl hydrazine International Journal of Chemical Studies, 4(1), pp109-1 l l, 2016.

A. Xavier, N. Srividhya, Synthesis and Study of Schiff base Ligands, IOSR Journal of Applied Chemistry, vol 7, pp 06-15, 2014.

Anant Prakash, Devjani Adhikari, Application of Schiff base and their metal complexes-A review, International journal of Chemtech research, Vol. 3, No.4, pp 1891-1896, 2011.

Sadia Afrin Dalia, Farhana Afsan, Md. Saddaln Hossain, Md. Nuruzzaman Khan, CM Zakaria, Md. Kudrat-E-Zahan and Md. Mahasin Ali, A short review on chemistry of Schiff base metal complexes and their catalytic application, International Journal of Chemical Studies, vol. 6, PP 2859- 2866, 2018.

R Antony, S. Theodore David, K Karuppasamy, K.Saravanan, S. Thanikaikarasan, S. Balakumar, Structural, Surface, Thermal and Catalytic Properties of Chitosan Supported Cu(II) Mixed Ligand Complex Materials. Journal of Surface Engineered Materials and Advanced Technology, 2, 284-29, 2012.

P. Supriya Prasad, Thandapani Gomathi and P. N. Sudha, Synthesis and Characterisation of Chitosan Schiff Base (CSB) and its Polyethylene Glycol Blend, vol 7, 2, pp 57-63, 2017.

Sadia Rashid, Chensi Shen, Jing Yang and Jing Li, Preparation and properties of chitosan-metal complex: Some factors influencing the adsorption capacity for dyes in aqueous solution, Journal of environmental science, vol. 66, pp301-309, 2017.

F Ahamadi, Z Oveisi, S. Mohamadi Sadni and F Ammozar, Chitosan based hydrogels: characteristics and pharmaceutical applications, Res Pharm Sci. 10(1): 1–16., 2015.

Tyuterov, S.L., Yakubchik, M.S., Tarlakovskii, S.A., Etal., Khitozan – Biologicheski Aktivnoe, Ekologicheski Bezopasnoe Sredstvo, Povyshayushchee Ustoichivost’ Rastenii K Boleznyam, Chitosan: A Biologically Active, Environmentally Safe Agent Enhancing the Resistance of Plants to Diseases, Scientific reports, 11, pp 305-312, 2021.

K. R. Krishnapriya, M. Kandaswamy, A new chitosan biopolymer derivative /as metal-complexing agent: synthesis, characterization, and metal(II) ion adsorption studies, Carbohydrate Research 345(14), pp 2013-22, 2010.

Pradip Kumar D, Joydeep D and Tripathi VS. Chitin and Chitosan: chemistry, properties and applications. Journal of scientific and Industrial Research, 63, pp 20-31, 2004.

Changiz Karami, Keivan Ghodrati, Mina Izadi, Azita Farrokh, Sedigheh Jafari, Maryam Mahmoudiyani, And Nahid Haghnazari, A Fast Procedure For The Preparation Of Benzimidazole Derivatives Using Polymer-supported With Trifluoromethanesulfonic Acid As Novel And Reusable Catalyst, Journal of the Chilean Chemical Society, vol. 58, 3, pp 1914-1917, 2013.

Nomi Srestha1, Janmajoy Banerjee1, Sujiti Srivastava, A review on chemistry and biological significance of benzimidazole nucleus, Journal of Pharmacy, 04, 12, pp 28-44, 2017.

Nannapaneni , Atyam Vsss Gupta, Mi Reddy, Raidu Ch Sarva, Synthesis, Characterization, and Biological Evaluation of Benzimidazole Derivatives as Potential Anxiolytics, J Young Pharm, 2(3):273-9, 2010.


Refbacks

  • There are currently no refbacks.