Open Access Open Access  Restricted Access Subscription or Fee Access

Preparation and Characterization of Mixed Ligand Complexes of Cobalt(II) and Ni(II) salt of Phthalimide with Some Oxamic Acids

Ajay Agarwal, Virendra Mishra

Abstract


The mixed ligand complexes of oxamic acids with Co(II) and Ni(II) salt of phthalimide were prepared, where oxm= N-phenyl thio urea oxamic acid(NPTUOA),m-tolumide oxamic acid (m-TOA), N-pyrrazole oxamic acid & phth= Co(II) and Ni(II) salt of phthamlimide. These all mixed ligand complexes examined by their elemental analysis, melting points, UV-visible analysis, I.R studies, magnetic susceptibility measurements and thin layer chromatography. Elemental analysis of the complexes shows 1:2 (Metal:Ligand) stiochiometry for all the complexes having the general formula of K2[M(oxm)2(phth)2]. On the basis of above studies an octahedral geometry is proposed for all above complexes. Keywords: co(II) and Ni(II) salt of phthalimide and octahedral geometry, oxamic acids

Full Text:

PDF

References


Philipe Arrizabalaga,Paule Caston, Jean Pierre Laurent, Transition Metal Chemistry,5(1),204-206, 1980.

Sabina Zagan, Ticuţa Negreanu– Pirjol Ovidius” University Annals of Medical Science – Pharmacy, Volume IV, Number 1, 2006.

S.J.Lippard, Angew.Chem.Engl., 27, 344, 1988.

R.L.Carrol, C.B.Gorman, Angew., 2002 Chem.Int., 41, 4378.

M. N. Hughes. The Inorganic Chemistry of Biological Processes, 2nd Edn., John Wiley & Sons: New York. 1981.

S.C.Lemos,S.J.S.Franchi,A.V.G.Netto,A.E.Mauro,O.TreuFilho,R.C.G.Frem,E.T.Almeida,C.Torres, J.Therm.Anal.Calorim, 2011doi:10.1007/s10973-011-1494-9.7.C.T.Carvalho,F.J.Caires,L.S.Lima,M.Ionashiro,J.Therm.Anal.Calorim.2011,doi:10.1007/410973-011-1679-2.

S.E.Livingstone,J.D.Nolan,A.E.Mihkelson,Inorg.Chem.,7,1447,1968.

S.E.Livingstone,J.D.Nolan,A.E.Mihkelson,Inorg.Chem., 9,2545,1970.

B.Rosenberg,L. Van Camp, Cancer Res.,30,1799,1970.

S.P.perlepes,Th.F.Zafiropoulos,J.K.Kouinis,A.Galinos,Z.Naturforsch,36b,697-703,1981.

D.S.Goldman, Biochem.Biophys.Acta,45,27A,1960.

Parke-Davis & Co,British Patent,730910,1955.

J. K. Kouinis, J. M. Tsangaris,A. G. Galinos,Z. Naturforsch. 33b, 987, 1978.

K.A. Hoffmann,U.Enrhardt,Ber.,46,,1457,1913.

R.M.Burger,Struct.Bonding,97,287,2000.

O.Kahn,Adv.Inorg.Chem.,43,180,1995.

Samy Wafa, M.Abu, M.Rafat, J.Ind.Chem.Soc. 29A, 285, 1990.

G.B.Decon, R.J.Philips, Coord.Chem.Rev., 33, 227,1980.

K.Nakamoto,”Infrared and Raman Spectra of Inorganic and Coordination Compounds”,John Wiley,New York,1980.

L.J.Bellamy,”The Infrared Spectra of Complex Molecules”Methuen, London, 1962.

.A.G.Galinos, J.M.Tsangaris, J.K.Kouinis, Z.Naturforsch, 32b, 645, 1977. 23.Jr.P.C.Bailer,Reinhold,Newyork,p180,1956.

G.F.Svatos,C.Curran,J.V.Quaglino,J.Am.Chem.Soc.,77,23,6159,1955.

N.P. Stabbert,D.A.Thronton,Spectrosc.Lett.,3,83,1970.

Ajay Agarwal,Virendra Mishra, Satnam Arora,IJTCK,Vol3,Issue1,Page5,20017.

P.C.H.Mitchell,J.Iinorg.Nucl.Chem.,25,9639,1963.

A.B.P.Lever,D.ogden,J.Chem.Soc.,(A),2041,1967.

ABP Lever. Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968.

O.Bostrup,C.K. Jorgensen,Acta Chem.Scand,11,1223,1957.

R.L. Carlin, Trans. Met. Chem., 4, 211. 1968

R.L.Carlin,Trans.Met.Chem.,Marcel-Dakker,N.Y.Vol(I),Chapter(i),p.20,1965.


Refbacks

  • There are currently no refbacks.