Open Access Open Access  Restricted Access Subscription or Fee Access

Effects of Compatibilizer and Paper Sludge Content on the Performances of Thermoplastic Polymer Composites

Ruhul A. Khan, Haydar U Zaman

Abstract


One of the environmental issues affecting third-world countries is the economic use of lignocellulose waste, which is now being researched. Paper sludge (PS) composites will allow for the effective use of a waste material that is currently burned or buried, as well as the ability to lower the cost of the composite that is created. In this study, the mechanical and thermal
characteristics of environmentally friendly composites constructed from PS-reinforced recycled poly(ethylene terephthalate) (rPET) matrix with the addition of SEBS-g-MA as a compatibilizer are presented. A twin-screw extruder was used to analyze the effects of SEBS-g-MA addition
and various PS content (10, 20, and 30 wt%) on the tensile, flexural, and impact properties of the rPET/PS eco-friendly composites. When compared to rPET/SEBS-g-MA blend, the stiffness of composites dramatically enhanced. The impact strength of rPET was dramatically increased by the addition of SEBS-g-MA. Due of the rubbery features of the compatibilizer, the blend has reduced tensile and flexural properties. With more PS, the tensile and flexural moduli became better. The maximum values for the tensile and flexural strengths were observed with a loading
of 10% PS. The nonisothermal crystallization results showed that for the PS-reinforced Ncomposites, the temperature of onset crystallization and degree of crystallinity increased. Studies using thermogravimetric analysis showed that the thermal stability of the composites improved when PS was added, with the primary decomposition temperature being around 350 o C.


Full Text:

PDF

References


Singh AK, Bedi R, et al. Composite materials based on recycled polyethylene terephthalate and their properties–A comprehensive review. Composites Part B: Engineering. 2021; 219: 108928.

Chen CH, Chen CY, et al. Studies of glycolysis of poly (ethylene terephthalate) recycled from postconsumer soft‐drink bottles. I. Influences of glycolysis conditions. Journal of Applied

Polymer Science. 2001; 80: 943–948.

Benyathiar P, Kumar P, et al. Polyethylene Terephthalate (PET) Bottle-to-Bottle Recycling for the Beverage Industry: A Review. Polymers. 2022; 14: 2366.

García J, García F, et al.: Handbook of Engineering and Specialty Thermoplastics. John Wiley & Sons, Inc New York, NY, USA:; 2011.

Ardekani SM, Dehghani A, et al. Mechanical and thermal properties of recycled poly (ethylene terephthalate) reinforced newspaper fiber composites. Fibers and Polymers. 2014; 15: 1531–1538.

Zaman HU, Khan RA. Effect of fiber surface modifications on the properties of snake grass fiber reinforced polypropylene bio-composites. Journal of Adhesion Science and Technology. 2022;

: 1439–1457.

Zaman HU, Khan RA. Surface Modification of Plant-Drive Calotropis Gigantea Fiber Reinforced Polypropylene Composites. Progress in Applied Science and Technology. 2020; 12: 23–35.

Zaman HU, Khan RA. Surface Modified Benzoylated Okra

(Abelmoschus esculentus) Bast Fiber Reinforced Polypropylene Composites. Advanced Journal of Science and Engineering. 2022; 3:

–17.

Zaman HU, Khan RA, et al. The improvement of physicomechanical, flame retardant, and thermal properties of lignocellulosic material filled polymer composites. Journal of Thermoplastic Composite Materials. 2021: 08927057211048535.

Zaman HU, Khan RA. Effect of Surface Treatment on the Mechanical Features of Lady’s Finger Fibers Reinforced Polymer Composites. Journal homepage: www ijrpr com ISSN; 2582: 7421.

Zaman HU, Khan R. A novel strategy for fabrication and performance evaluation of bamboo/eglass fiber-reinforced polypropylene hybrid composites. International Journal of Research. 2021;8: 201–211.

Zaman HU, Khan RA. Acetylation used for natural fiber/polymer composites. Journal of Thermoplastic Composite Materials. 2021; 34: 3–23.

Oksman K, Clemons C. Mechanical properties and morphology of impact modified polypropylene-wood flour composites. Journal of Applied Polymer Science. 1998; 67:1503–1513.

Yam KL, Gogoi BK, et al. Composites from compounding wood fibers with recycled high density polyethylene. Polymer Engineering & Science. 1990; 30: 693–699.

Bogoeva‐Gaceva G, Avella M, et al. Natural fiber eco‐composites. Polymer Composites. 2007;28: 98–107

Raj R, Kokta B, et al. Compounding of cellulose fibers with polypropylene: Effect of fiber treatment on dispersion in the polymer matirx. Journal of Applied Polymer science. 1989; 38:1987–1996.

Son J, Kim HJ, et al. Role of paper sludge particle size and extrusion temperature on performance of paper sludge–thermoplastic polymer composites. Journal of Applied Polymer Science. 2001;

: 2709–2718.

Jang J, Lee E. Improvement of the flame retardancy of paper-sludge/polypropylene composite. Polymer Testing. 2000; 20: 7–13.

Girones J, Pardini G, et al. Recycling of paper mill sludge as filler/reinforcement in polypropylene composites. Journal of Polymer Environment. 2010; 18: 407–412.

Qiao X, Zhang Y, et al. Ink‐eliminated waste paper sludge flour‐filled polypropylene composites with different coupling agent treatments. Journal of Applied Polymer Science. 2003; 89: 513–520.

Marques S, Alves L, et al. Conversion of recycled paper sludge to ethanol by SHF and SSF using Pichia stipitis. Biomass and Bioenergy. 2008; 32: 400–406.

Ayrilmis N, Buyuksari U. Utilization of olive mill sludge in manufacture of lignocellulosic/polypropylene composite. Journal of Materials Science. 2010; 45: 1336–1342.

Ismail H, Rusli A, et al. The effect of partial replacement of paper sludge by commercial fillers on natural rubber composites. Journal of Reinforced Plastics and Composites. 2008; 27: 1877–1891.

Papke N, Karger-Kocsis J. Thermoplastic elastomers based on compatibilized poly (ethylene terephthalate) blends: effect of rubber type and dynamic curing. Polymer. 2001; 42: 1109–1120.

Hon DN-S, Buhion CJ. Composites from commingled polyethylene terephthalate, high-density polyethylene and newspaper fibers. Journal of Thermoplastic Composite Materials. 1997; 10:287–301.

Zhang Y, Zhang H, et al. Crystallization and mechanical properties of recycled poly (ethylene terephthalate) toughened by styrene–ethylene/butylenes–styrene elastomer. Journal of Polymer

Environment. 2010; 18 :647–653.

Yu ZZ, Yang MS, et al. Toughening of recycled poly (ethylene terephthalate) with a maleic anhydride grafted SEBS triblock copolymer. Journal of Applied Polymer Science. 2004; 93:1462–1472.

Dehghani A, Ardekani SM, et al. Mechanical and thermal properties of date palm leaf fiber reinforced recycled poly (ethylene terephthalate) composites. Materials & Design (1980-2015).

; 52: 841–848.

Ismail S, ABU BA. A comparative study on the effects of paper sludge and kaolin on properties of polypropylene/ethylene propylene diene terpolymer composites. Iranian Polymer Journal. 2005; 14: 705–713.

Son J, Yang H-S, et al. Physico-mechanical properties of paper sludge-thermoplastic polymer composites. Journal of Thermoplastic Composite Materials. 2004; 17: 509–522.

Azwa Z, Yousif B, et al. A review on the degradability of polymeric composites based on natural fibres. Materials & Design. 2013; 47: 424–442


Refbacks

  • There are currently no refbacks.