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A Comprehensive Characterization of Zinc Chloride: Unveiling its Role as a Hygroscopic Preservative and Drying Agent through Elemental, Structural, and Morphological Analysis

Joseph A. Owolabi, Eyitayo Marion Oloruntoba

Abstract


This study presents a detailed investigation of Zinc Chloride( )) utilizing the following different analytical techniques, X-ray diffraction(XRD), Electron Dispersive Spectroscope (EDS), Transmission Electron Microscope (TEM), Scanning Electron Microscope (SEM). Zinc Chloride was synthesized using the hydrothermal method. The elemental, structural, morphological, and optical properties of Zinc Chloride ( )) were thoroughly analyzed. The hygroscopic nature and properties of Zinc Chloride upon exposition to air was revealed and its weight/mass measurement was done within five days at the same time interval. EDS measurements show the composition of zinc chloride with a dominant weight percentage of Zinc of 77.76%, Chlorine weight of 2.00%, and oxygen of 20.24% serving as an impurity or contaminant. SEM) scanning electron microscope observations indicated crystal agglomeration, smooth surfaces, absence of hair-like textures, and a minimal presence of impurities within the zinc chloride sample. Moreover, the SEM analysis indicated that zinc chloride exhibited a rod-like crystal morphology. X-ray diffraction (XRD) revealed phase identification of the sample, crystallographic texture, and residual stress and strain of the sample. TEM visualized the particle size distribution, crystal shapes, and surface characteristics. The atomic values of in percentage is 55.00, 5.22, and 39.78 respectively. The shape of Zinc Chloride particle is hexagonal and the particle size ranges between 3.22nm and 15.30nm when the wavelength is 100nm. The hygroscopic nature of zinc chloride was confirmed upon exposure to ambient air. Based on the findings, this research unequivocally establishes zinc chloride as a hygroscopic compound with significant potential for application as a preservative and desiccant across diverse industrial domains.

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References


Lu, X and Shen, X. (2011). Solubility of Bacteria Cellulose in Zinc Chloride Aqueous Solutions. Carbohydr. Polym., 86, 239−244.

Mukharya, A., Chaudhary, S., Mansuri, N., Misra, A.K. (2012). Solid-state characterization of lacidipine/PVP K(29/32) solid dispersion primed by solvent co-evaporation. Int J Pharm Investig.2:90–6.

Nath, A., Atkins, W.M., Sligar, S.G.(2007). Applications of phospholipid bilayer nanodiscs in the study of membranes and membrane proteins. Vol(8): 2059-2069.

Owolabi,J.A and Oloruntoba,M.E(2023). Preparation and characterization of zinc chloride through hydrothermal synthesis. Journal of Emerging Technologies and Innovative Research. Vol. 10(8), 1598-1603.

Raut, N.S., Deshmukh, P.R, Umekar, M.J, Kotagale, N.R. (2013). Zinc cross-linked hydroxamated alginates for pulsed drug release. Int J Pharm Investig.; 3:194–202.

Sardar B., Alam, J. Y., Karen, C., Bustillo, C. O., Peter, E., Haimei, Z., Emory, M.C. (2020). Hybrid nanocapsules for in situ TEM imaging of gas evolution reactions in confined liquids , Nanoscale, 10.1039/D0NR05281G, 12, 36, (18606-18615).

Tallo, I., Thomberg, T., Kurig, H., Jänes, A., Kontturi, K., Lust E. (2013). Supercapacitors Based on Activated Silicon Carbide-Derived Carbon Materials and Ionic Liquid. The Electrochemical Society Journal, Volume 163, Number 7.

Titirici, M.M. (2013). Sustainable carbon materials from hydrothermal processes, p. 357, Wiley, Chichester.

Toprak, A and Kopac, T. (2017) Carbon Dioxide Adsorption Using High Surface Area Activated Carbons from Local Coals Modified by KOH, NaOH and ZnC Agents January 2017 International Journal of Chemical Reactor Engineering 15(3) DOI: 10.1515/ijcre-2016-0042.

Toprak, A and Kopac, T. (2018) Effect of Surface Area and Microspore Volume of Activated Carbons from Coal by KOH, NaOH and ZnC Treatments on Methane Adsorption International Journal of Chemical Reactor Engineering 17(6) DOI:10.1515/ijcre-2018-0146.

Wood, D., Vailati, C., Menges, A., Rüggeberg, M. (2018). Hygroscopically actuated wood elements for weather responsive and self-forming building parts – Facilitating upscaling and complex shape changes. Construction and Building Materials. 2018;165:782–791. doi: 10.1016/j.conbuildmat.2017.12.134.

Yang, L., Li, G., Yang, F., Zhang, S.M., Fan, H.X., Lv, X.N. (2011). Direct Conversion of Cellulose to 1-(furan-2-yl)-2-hydroxyethanone in Zinc Chloride Solution under Microwave Irradiation. Carbohydr. Res., 346, 2304−2307.

Feng. S, Li(2017). Photo- Stabilization properties of transparent inorganic UV-filter nanocomposites. Sciece Techology 67, 3465- 3471.




DOI: https://doi.org/10.37628/jtck.v9i2.1459

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